White has not played for England since a 3-0 friendly win against Ivory Coast in March 2022.
He replaces Jarell Quansah in Thomas Tuchel’s expanded 35-man squad after the Bayer Leverkusen defender was ruled out with a thigh injury.
Real Madrid defender Trent Alexander-Arnold was overlooked for the fourth successive England squad.
After Real’s derby victory over Atletico Madrid on Sunday, he wrote on Instagram: “Madrid. And nothing else.”
White has made only seven Premier League appearances for leaders Arsenal this season.
However, he has played in eight of their 10 Champions League games in their run to the quarter-finals and started Sunday’s 2-0 Carabao Cup final defeat by Manchester City.
